Emergent Nanostructure and Ion Transport in Polyzwitterion/Polyanion Blends
- Li, Hongwei | Texas A&M University
- Zhu, Qinyu | Oak Ridge National Laboratory
- Shinohara, Yuya | Oak Ridge National Laboratory
- Wang, Yangyang | Oak Ridge National Laboratory
- Christakopoulos, Panagiotis | Oak Ridge National Laboratory
- Huang, Zitan | The Pennsylvania State University
- Bonnesen, Peter V. | Oak Ridge National Laboratory
- Do, Changwoo | Oak Ridge National Laboratory
- Lehmann, Michelle | Oak Ridge National Laboratory
- Saito, Tomonori | Oak Ridge National Laboratory
- Colby, Ralph H. | The Pennsylvania State University
- Kumar, Rajeev | Oak Ridge National Laboratory
- Lutkenhaus, Jodie L. | Texas A&M University
Overview
Description
We investigated blends of poly(1-(3-sulfonatopropyl)-2-vinylpyridinium) (P2VPPS) and poly(lithium (trifluoromethane)sulfonimide methacrylate) (poly(MTFSI)Li) at varying molar ratios to gain a mechanistic understanding of ionic conductivity in a miscible polyzwitterion/polyanion system. This dataset contains the raw numerical data corresponding to the figures in the manuscript. The data files include the following information:
(1) Experimental Data – includes X-ray and neutron scattering measurements, broadband dielectric spectroscopy (BDS) data, extracted DC conductivity values, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) results, extracted glass transition temperatures, etc.
(2) CGMD Data – includes molecular dynamics (MD) trajectory files and computed structural correlations.
All data files are organized/named according to the figure numbers in the manuscript.
Funding Resources
DOE Contract Number
DE-AC05-00OR22725Originating Research Organization
Texas A&M UniversityOther Contributing Organizations
Oak Ridge National Laboratory; The Pennsylvania State UniversitySponsoring Organization
Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Texas A&M University Soft Matter Facility (RRID SCR_022482)Related Resources
- IsSupplementTo (DOI): https://doi.org/10.1021/acs.macromol.5c00806
Details
DOI
10.13139/ORNLNCCS/2529465Release Date
August 5, 2025Dataset
Dataset Type
ND Numeric DataSoftware
Microsoft Excel, Text Editor, OvitoAcknowledgements
Users should acknowledge the OLCF in all publications and presentations that speak to work performed on OLCF resources:
This work was carried out [in part] at Oak Ridge National Laboratory, managed by UT-Battelle, LLC for the U.S. Department of Energy under contract DE-AC05-00OR22725.
Category
- 36 MATERIALS SCIENCE
Keywords
- Polyzwitterion,
- Polyanion,
- WAXS,
- SANS,
- SAXS,
- Coarse-grained MD,
- Glass Transition Temperature,
- Ionic Conductivity,
- Complex Formation